BA 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 BB 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 ZA 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 ZB 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 CA 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 CB 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 PA 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 PB 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200

FULL TEST 05

BOTANY

Section-A

1.Match List I with List II and select the correct answer -

List I List II
A. Cyanophyta (i) Chrysolaminarin
B. Chlorophyata (ii) Amylopectin
C. Phaeophyta (iii) Floridean starch
D. Rhodophyta (iv) Starch
(v) Laminarin

A-(ii),B-(v),C-(i),D-(iii)
A-(ii),B-(iv),C-(v),D-(iii)
A-(i),B-(iv),C-(iii),D-(v)
A-(ii),B-(iii),C-(v),D-(i)

2.Which one of the following is a true fruit?

Apple
Pear
Cashew nut
Coconut

3.Which of the following meristem is also called ‘file meristem’ ?

mass meristem
plate meristem
inter calary meristem
none of these

4.Which of the following algae are suitable for human consumption?

Laminaria and Fucus
Gracilaria and Chondrus
Porphyra and Spirogyra
Rhodymania and Porphyra

5.Which of the following organelles is directly connected to the outer membrane of the nucleus in a eukaryotic cell?

Mitochondrion
Lysosome
Golgi apparatus
Endoplasmic reticulum

6.Chosse the correct combinations.

I. Hypogynous flower
II. Perigynous flower
III. Epigynous flower

A - I, B - II, C - III
A - I, B - III, C - II
A - III, B - II, C - I
A - III, B - I, C - II

7.Formation of diploid embryo sac from diploid vegetative structure is called :

Diplospory
Apospory
Adventive polyembryony
Apomixis

8.Entry of pollen tube through micropyle is

Chalazogamy
Mesogamy
Porogamy
Pseudogamy

9.Competition for light, nutrients and space is most severe between

closely related organism growing in different habitats
closely related organisms growing in the same habitat
distantly related organisms growing in the same habitat
distantly related organisms growing in different habitats

10.From megasporocyte to egg cell, what processes are required ?

Meiosis followed by mitosis
Mitosis followed by meiosis
Several meiotic divisions only
Several mitotic divisions only

11.Which one of the following pairs is not correctly matched ?

Production of sulphur dioxide - Burning of coal
Depletion of ozone layer - Release of CFCs layer in the atmosphere
Eutrophication - Increase in nitrogen and phosphorus content in auatic bodies
Decrease in BOD of pond water - Increase in global temperature

12.The electrostatic precipitator is used for removing particulate matter from

Exhaust of the thermal power plant
Exhaust from the automobiles
Industrial effluents
Kitchen waste

13.Keystone species in an ecosystem are those

present in maximum number
that are most frequent
attaining a large biomass
contributing to ecosystem properties

14.If the gene encoding the trp repressor is mutated such that it can no longer bind tryptophan, will transcription of the trp operon occur?

Yes, because the trp repressor can only bind the trp operon and block transcriptional initiation when it is bound to tryptophan
No, because this mutation does not affect the part of the repressor that can bind the operator
No, because the trp operon is repressed only when tryptophan levels are high
Yes, because the trp operon can allosterically regulate the enzymes needed to synthesize the amino acid tryptophan.

15.What is the best pH of soil for cultivation of plants ?

3.4 – 5.4
6.5 – 7.5
4.5 – 8.5
5.6 – 6.5

16.Telomerase is an enzyme which is a

simple protein
RNA
ribonucleoprotein
repetitive DNA

17.Mass of living matter at a trophic level in an area at any time is called

standing crop
deteritus
humus
standing state

18.The Triticale is an intergeneric hybrid between :

wheat and maize
maize and rye
wheat and rye
bajra and wheat

19.Choose the correct option.

A – Plasma membrane, B – Interdoublet bridge, C – Central microtubule, D – Radial spoke
A – Plasma membrane, B – Arm, C – Central microtubule, D – Radial spoke
A – Plasma membrane, B – Interdoublet bridge, C – Hub, D – Radial spoke
A – Plasma membrane, B – Interdoublet bridge, C– Hub, D – Arm

20.An ecosystem which can be easily damaged but can recover after some time if damaging effect stops will be having

low stability and high resilience
high stability and low resilience
low stability and low resilience
high stability and high resilience

21.The mode of catching insects in Drosera plants is by means of

sensitive glandular hairs which secrete a sweet, viscous, shining substance.
specially sensitive trigger hairs.
leaves which are modified into pitcher.
leaf segments modified into bladder.

22.Quantasomes are present in

chloroplast
mitochondria
golgi body
lysosome

23.What is the minimum number of cell membranes that a water molecule must move through in getting from the soil into a xylem vessel element ?

0
1
2
6

24.Which of the following statements regarding photorespiration are true ?

Photorespiration is a metabolically expensive pathway.
Photorespiration is avoided when carbon dioxide is abundant.
Photorespiration results in a loss of usable carbon dioxide.
All of the above.

25.A free living nitrogen-fixing cyanobacterium which can also form symbiotic association with the water fern Azolla is

Tolypothrix
Chlorella
Nostoc
Anabaena

26.Which of the following statements correctly characterizes changes in $CaCO_3$, clay and biomass during the long-term aging of soil?

$CaCO_3$ gradually decreases, clay gradually increases and biomass peaks and then declines.
$CaCO_3$ gradually decreases, clay and biom- ass gradually increase.
Clay gradually increases, $CaCO_3$ and biom- ass peak and then decline.
All three gradually decrease.

27.Krebs cycle occurs in

mitochondria
cytoplasm
chloroplasts
ribosomes

28.Most abundant organic compound on earth is

Protein
Cellulose
Lipids
Steroids

29.An inhibitor is added to a cell culture so that succinate accumulates. The enzyme catalysing the formation of which substance has been blocked?

Citrate
Oxaloacetate
alpha-ketoglutarate
Fumarate

30.To avoid excessive water loss during severe drought stress, the closure of stomata is signalled by the production of

IAA
NAA
ABA
IBA

31.The amount of DNA in a mammalian cell in early prophase I is x.What is the amount of DNA in the same cell in anaphase I of meiosis?

x/4
x/2
x
2x

32.The major reason that glycolysis is not as energy productive as respiration is that

NAD$^+$ is regenerated by alcohol or lactate production, without the high-energy electrons passing through the electron transport chain.
it is the pathway common to fermentation and respiration.
it does not take place in a specialized membrane-bound organelle.
pyruvate is more reduced than CO$_2$; it still contains much of the energy from glucose.

33.All the following statements are true with regard to Km value, except :

Km is defined as the substrate concentration at half maximal velocity
Then 50% of enzyme molecules are bound with substrate molecules
Km is independent of enzyme concentration
As numerical value of Km is more, the affinity of enzyme to substrate is more

34.Biodiversity Act of India was passed by the parliament in the year

1992
1996
2000
2002

35.Which one thing is not true about antibiotics?

The term “antibiotic” was coined by Selman Waksman in 1942
First antibiotic was discovered by Alexander Flemming
Each antibiotic is effective only against one particular kind of germ
Some persons can be allergic to a particular antibiotic

BOTANY

Section-B

36.Which one is a neem product used as insect repellent?

Azadirachtin
Rotenone
Parathione
Endrin

37. ‘Axenic culture’ is

culture of tissue
growing of shrubs
growing of tall trees
culture of tissue free from contamination

38.Which of the following is an antinutritional factor in Brassica napus ?

Hirudin
Erucic acid and glucosinolates
Amygdalin
Cyanophycean granules

39.The common nitrogen fixer in paddy fields is

Rhizobium
Azospirillum
Oscillatoria
Frankia

40.In order to obtain virus- free plants through tissue culture, the best method is

protoplast culture
embryo rescue
anther culture
meristem culture

41.Rennet is purified by C. Hansen (1874) for commercial use. This enzyme is extracted from

Stomach of goat
Stomach of horse
Stomach of calf
Bacteria

42.

Which of the above is Zwitterionic form?

A
B
C
All of these

43.Restriction endonucleases are enzymes which

make cuts at specific positions within the DNA molecule
recognize a specific nucleotide sequence for binding of DNA ligase
restrict the action of the enzyme DNA polymerase
remove nucleotides from the ends of the DNA molecule

44.Consider the following four statements (i-iv) and select the option which includes all the correct ones only.
(i) Single cell Spirulina can produce large quantities of food rich in protein, minerals, vitamins etc.
(ii) Body weight-wise the micro-organism Methylophilus methylotrophus may be able to produce several times more proteins than the cows per day.
(iii) Common button mushrooms are a very rich source of vitamin C.
(iv) A rice variety has been developed which is very rich in calcium.

Statements (ii) and (iv)
Statements (i), (iii) and (iv)
Statements (ii), (iii) and (iv)
Statements (i) and (ii)

45.Biome is

Sum of ecosystems in a geographical area
Sum of ecosystems of the whole earth
Biotic component of an ecosystem
Biotic potential of a population

46.The slow rate of decomposition of fallen logs in nature is due to their

low moisture content
poor nitrogen content
anaerobic environment around them
low cellulose content

47.Which one of the following is not included under in-situ conservation?

Botanical garden
Biosphere reserve
National park
Sanctuary

48.Chipko movement was launched for the protection of

forests
livestock
wet lands
grasslands

49.Which is a sex influenced trait?

Baldness in man
Hairy pinna
Porcupine skin in man
Colourblindness in man

50.Vasa efferentia are the ductules leading from

testicular lobules to rete testis
rete testis to vas deferens
vas deferens to epididymis
epididymis to urethra

ZOOLOGY

Section-A

51.Sex factor in bacteria is

Chromosomal replicon
F-replicon
RNA
Sex-pilus

52.Animals/organisms floating on the surface of water are

plankton
pelagic
benthos
neritic

53.Which layer is very thick at the sole and palm and is water proof?

Stratum granulosum
Stratum lucidium
Stratum corneum
Stratum spongiosum

54.Spleen is referred to as

temporary endocrine gland
graveyard of RBC
largest gland
store house of WBC

55.Given below are four matchings of an animal and its kind of respiratory organ :
(i) Silver fish – trachea
(ii) Scorpion – book lung
(iii) Sea squirt – pharyngeal gills
(iv) Dolphin – skinThe correct matchings are

(iii) and (iv)
(i) and (iv)
(i), (ii) and (iii)
(ii) and (iv)

56.In the mouthparts of the cockroach, the organ of mastication is

labium
maxillae
mandibles
labrum

57.Which one of the following characters is not typical of the class Mammalia?

Thecodont dentition
Alveolar lungs
Ten pairs of cranial nerves
Seven cervical vertebrae

58.Natural parthenogenesis occurs in:

Protozoans
Earthworm
All insects
Honeybee

59.Consider the statements given below regarding contraception and answer as directed thereafter:
(i) Medical Termination of Pregnancy (MTP) during first trimester is generally safe
(ii) Generally chances of conception are nil until mother breast-feeds the infant upto two years
(iii) Intrauterine devices like copper-T are effective contraceptives
(iv) Contraception pills may be taken upto one week after coitus to prevent conception
Which two of the above statements are correct?

(ii) and (iii)
(iii) and (iv)
(i) and (iii)
(i) and (ii)

60.Identify the blood vessels A to D.


A- Systemic vein, B-Pulmonary artery, C-Pulmonary vein, D-Systemic artery
A-Systemic artery, B-Pulmonary artery,C- Pulmonary vein, D- Systemic vein
A-Pulmonary artery, B-Systemic vein,C-Pulmonary vein, D- Systemic artery
C-Pulmonary vein, D- Systemic artery,C- Pulmonary artery, D- Systemic artery

61.Which pathway of the male reproductive system is correct for the sperms transportation?

Vas efferentia$→$Vas deferens$→$Epididymis
Vas deferens$→$Epididymis$→$Seminal vesicle
Epididymis$→$Vas deferens$→$Urethra
Rete testis$→$Epididymis$→$Vas efferentia

62.The second maturation division of the mammalian ovum occurs:

in the Graafian follicle following the first maturation division
Shortly after ovulation before the ovum makes entry into the fallopian tube
Until after the ovum has been penetrated by a sperm
Until the nucleus of the sperm has fused with that of the ovum

63.A force acting against achievement of highest possible level of population growth is

Carrying capacity
Environment resistance
Population pressure
Saturation level

64.The phase of menstrual cycle in humans that lasts for 7-8 days, is

follicular phase
ovulatory phase
luteal phase
menstruation

65.What type of human population is represented by the following age pyramid?


Vanishing population
Stable population
Declining population
Expanding population

66.The 'Mule' is the result of

Inbreeding depression
Out breeding
Cross breeding
Inter-specific hybridization

67.Haemophilia is more common in males because it is a

Recessive character carried by Y–chromosome
Dominant character carried by Y-chromosome
Dominant trait carried by X-chromosome
Recessive trait carried by X-chromosome

68.Theory of inheritance of acquired characters was given by

Wallace
Lamarck
Darwin
De Vries

69.The animal husbandry deals with the care, breeding and management of

Domesticated animals
Fishes
Honey bees and silk worms
All of these

70.‘Inland fishery’ refers to

Culturing fish in fresh water
Trapping and capturing fishes from sea coast
Deep sea fishing
Extraction of oil from fishes

71.The diagram below shows the parasympathetic innervation of the smooth muscle and glands of the stomach.

What chemical transmitters are released at the synapses X and Y ?

X-Acetylcholine, Y-Acetylcholine
X-Acetylcholine, Y-Calcium ions
X-Acetylcholine, Y-Noradrenaline
X-Noradrenaline, Y-Calcium ions

72.Which of following teeth are lophodont?

Incisor and canine
Premolar and molar
Canine and premolar
Premolar and incisor

73.Pacemaker of heart is

AV node
Bundle of His
SA node
Purkinje fibres

74.Uricotelism is found in

Frogs and toads
Mammals and birds
Birds, reptiles and insects
Fishes and fresh water protozoans

75.A large proportion of oxygen is left unused in the human blood even after its uptake by the body tissues. This O$_2$

acts as a reserve during muscular exercise
raise the pCO$_2$ of blood to 75 mm of Hg
is enough to keep oxyhaemoglobin saturation at 96%
helps in releasing more O$_2$ to the epithelial tissues.

76.The basic functional unit of the human kidney is

nephron
nephridia
pyramid
Henle’s loop

77.Urea from the blood can be removed by

Uremia
Diuresis
Dialysis
Micturition

78.What prevents molecules with a molecular mass greater than 68000 passing from the glomerular capillaries into Bowman’s capsule?

the basement membrane of the epithelial cells of Bowman’s capsule
the cell surface membrane of the endothelial cells of the capillaries
the cell surface membrane of the epithelial cells of Bowman’s capsule
the spaces between the extensions of the podocytes of Bowman’s capsule

79.The nerve centres which control the body temperature and the urge for eating are contained in:

hypothalamus
pons
cerebellum
thalamus

80. Rods and cones of eyes are modified

multipolar neuron
unipolar neuron
bipolar neuron
None of these

81.A patient with a pituitary tumor might suffer with polyuria (production of too much urine) as a result of decreased secretion of

MSH
FSH
aldosterone
ADH

82.The sensation of fatigue in the muscles after prolonged strenuous physical work, is caused by

a decrease in the supply of oxygen
minor wear and tear of muscle fibres
the depletion of glucose
the accumulation of lactic acid

83.Consider the diagram given below

Identify the labelled parts as A, B, C, D and E respectively.

Frontal bone, Parietal bone, Temporal bone, Occipital condyle and Hyoid bone
Frontal bone, Temporal bone, Parietal bone, Occipital condyle and Hyoid bone
Frontal bone, Parietal bone, Temporal bone, Hyoid bone and Occipital condyle
Parietal bone, Frontal bone, Temporal bone, Occipital condyle and Hyoid bone

84.Which one of the following statements is incorrect ?

The presence of non-respiratory air sacs, increases the efficiency of respiration in birds.
In insects, circulating body fluids serve to distribute oxygen to tissues.
The principle of countercurrent flow facilitates efficient respiration in gills of fishes.
The residual air in lungs slightly decreases the efficiency of respriration in mammals.

85.The residual air in lungs slightly decreases the efficiency of respriration in mammals.

Epinephrine
Norepinephrine
Cortisone
Acetylcholine

ZOOLOGY

Section-B

86.An animal with same generic, specific and subspecific names is

man
gorilla
rabbit
elephant

87.A meal containing snails, clams and octopus represents which of the following classes of molluscs ?

Bivalvia only
Gastropoda and Cephalopoda
Bivalvia and Gastropoda
Bivalvia, Gastropoda and Cephalopoda

88.Which one of the following statements is correct?

Neurons regulate endocrine activity, but not vice versa.
Endocrine glands regulate neural activity and nervous system regulates endocrine glands.
Neither hormones control neural activity nor the neurons control endocrine activity.
Endocrine glands regulate neural activity but not vice versa.

89.‘Cloning’ is meant for/to

production of hGH gene in E. coli
preserve the genotype of organism
replace the original gene
All of the above

90.A cell coded protein formed in response to infection with most animal viruses is

Antigen
Antibody
Interferon
Histone

91.Which one of the following is not used in organic farming?

Glomus
Earthworm
Oscillatoria
Snail

92.ELISA is used to detect viruses where the key reagent is

RNase
alkaline phosphatase
catalase
DNA probe

93.Vitamin B$_{12}$ is formed during fermentation of

Ashloya gossipii
Rhizopus stolonifer
Propionibacteria
Saccharomyces cerevisiae

94.Which of the following pairs is not correctly matched ?

Dengue fever – Arbovirus
Plague – Yersinia pestis
Syphilis – Trichuris trichura
Sleeping sickness – Trypanosoma gambiense

95.Which one of the following depresses brain activity and produced feelings of calmness, relaxation and drowsiness?

Morphine
Valium
Amphetamines
Hashish

96.Which one of the following is correctly matched pair of the given secretion and its primary role in human physiology?

Sebum — Sexual attraction
Sweat — Thermoregulation
Saliva — Tasting food
Tears — Excretion of salts

97.Where will you look for the sporozoites of the malarial parasite?

Saliva of infected female Anopheles mosquito
Red blood corpuscles of humans suffering from malaria
Spleen of infected humans
Salivary glands of freshly moulted female Anopheles mosquito

98.Which of the following insects is useful for us?

Musca
Bombyx
Pheretima
Periplaneta

99.There is a restriction endonuclease called EcoRI. What does co. part in it stand for?

Colon
Coelom
Coenzyme
Coli

100.Genetically engineered bacteria have been successfully used in the commercial production of

human insulin
testosterone
thyroxine
melatonin

CHEMISTRY

Section-A

101.An acidic solution of 'X' does not give precipitate on passing H$_2$S through it. 'X' gives white precipitate when NH$_4$OH is added to it. The white precipitate dissolves in excess of NaOH solution. Pure 'X' fumes in air and dense white fumes are obtained when a glass rod dipped in NH$_4$OH is put in the fumes. Compound 'X' can be

$ZnCl_2$
$FeCl_3$
$AlCl_3$
$SnCl_2$

102.$CN^-$ is a strong field ligand. This is due to the fact that

it carries negative charge
it is a pseudohalide
it can accept electrons from metal species
it forms high spin complexes with metal species

103.The amount of arsenic pentasulphide that can be obtained when 35.5 g arsenic acid is treated with excess H$_2$S in the presence of conc. HCl (assuming 100% conversion) is :

0.25 mole
0.50 mole
0.333 mole
0.125 mole

104.Which one of the following statement is not true ?

pH of drinking water should be between 5.5 – 9.5.
Concentration of DO below 6 ppm is good for the growth of fish.
Clean water would have a BOD value of less than 5 ppm.
Oxides of sulphur, nitrogen and carbon are the most widespread air pollutant.

105.Which property of white phosphorus is common to red phosphorous ?

It burns when heated in air.
It reacts with hot caustic soda solution to give phosphine.
It shows chemiluminescence.
It is soluble in carbon disulphide

106.Heat of dissociation of CH$_3$COOH is 0.005 kcal/g, hence enthalpy change when 1 mole of Ca(OH)$_2$ is completely neutralised by CH$_3$COOH is

– 27.4 kcal
– 13.6 kcal
– 26.8 kcal
– 27.1 kcal

107.0.4 moles of HCl and 0.2 moles of $CaCl_2$ were dissolved in water to have 500 mL of solution, the molarity of Cl$^-$ ion is:

0.8 M
1.6 M
1.2 M
10.0 M

108.In sodium fusion test of organic compounds, the nitrogen of the organic compound is converted into

Sodamide
Sodium cyanide
Sodium nitrite
Sodium nitrate

109. A + 2B + 3C $⇄$ $AB_2C_3$
Reaction of 6.0 g of A, 6.0 × 10$^{23}$ atoms of B, and 0.036 mol of C yields 4.8 g of compound $AB_2C_3$ . If the atomic mass of A and C are 60 and 80 amu, respectively, the atomic mass of B is (Avogadro no. = 6 × 10$^{23}$)

50 amu
60 amu
70 amu
40 amu

110.Inductive effect involves

displacement of σ-electrons
delocalisation of π-electrons
delocalisation of σ-electrons
displacement of π-electrons

111.Arrange the following elements in the order of ease of detection of wave properties, in the de Broglie experiment.
H, Li, Be, B, K

H < Be, B < Li < K
H > Li > K > Be > B
H > Li > Be > B > K
H < Li < Be < B < K

112.The decreasing order of stability of alkyl carbonium ion is in the order of :


(a)
(b)
(c)
(d)

113.Aluminium vessels should not be washed with materials containing washing soda since

washing soda is expensive
washing soda is easily decomposed
washing soda reacts with Al to form soluble aluminate
washing soda reacts with Al to form insoluble aluminium oxide

114.The following data are for the decomposition of ammonium nitrite in aqueous solution :

Volume of $N_2$ in cc Time (min)
6.25 10
9.00 15
11.40 20
13.65 25
35.65 Infinity

The order of reaction is :

Zero
One
Two
Three

115.Which of the following reagents convert propene to 1-propanol?

$H_2O$, $H_2SO_4$
aqueous KOH
$MgSO_4$, $NaBH_4/H_2O$
$B_2H_6$, $H_2O_2$, $OH^-$

116.A closed container contains equal number of oxygen and hydrogen molecules at a total pressure of 740 mm. If oxygen is removed form the system then pressure will

Become double of 740 mm
Become half of 740 mm
Become 1/9 of 740 mm
Remains unchanged

117.Compound X of molecular formula $C_4H_6$ takes up one equivalent of hydrogen in presence of Pt to form another compound Y which on ozonolysis gives only ethanoic acid. The compound X can be

$CH_2=CH-CH=CH_2$
$CH_2=C=CHCH_3$
$CH_3C≡CCH_3$
All of these

118.1 M solution of CH$_3$COOH should be diluted to ............... times so that pH is doubled.

four times
5.55 × 10$^4$ times
5.55 × 10$^6$ times
$10^{-2}$ times

119.The following reactions take place in the blast furnace in the preparation of impure iron. Identify the reaction pertaining to the formation of the slag.

$Fe_2O_{3(s)}$ + 3CO$_{(g)}$ $→$ 2Fe$_{(l)}$ + 3CO$_{2(g)}$
$CaCO_{3(g)}$ $→$ $CaO_{(s)}$ + $CO_{2(g)}$
$CaO_{(s)}$ + $SiO_{2(s)}$ $→$ $CaSiO_{3(s)}$
$2C_{(s)}$ +$O_{2(g)}$ $→$ $2CO_{(g)}$

120.Which one of the following is NOT a buffer solution?

0.8 M $H_2S$ + 0.8 M KHS
2M$C_6H_5NH_2$ + 2M$C_6H_5N^+H_3Br^-$
$3MH_2CO_3$ + 3M$KHCO_3$
0.05M$KClO_4$ + 0.05M$HClO_4$

121.Which of the following statements is false ?

Radon is obtained from the decay of radium
Helium is inert gas
Xenon is the most reactive among the rare gases
The most abundant rare gas found in the atmosphere is helium

122.Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine)

cis-$[Pt(NH_3)_2Cl_2$]
trans-$[Pt(NH_3)_2Cl_2$]
cis-$[Co(en)_2Cl_2$]
trans-$[Co(en)_2Cl_2$]

123.The bromination of acetone that occurs in acid solution is represented by this equation.
$CH_3COCH_{3(aq)}$ + $Br_{2(aq)}$ $→$ $CH_3COCH_2Br_{(aq)}$ + $H^+_{(aq)}$ + $Br^-_{(aq)}$
These kinetic data were obtained for given reaction concentrations.

Initial Concentrations M Initial rate of disappearance of $Br_2$, $Ms^{-1}$
$[CH_3COCH_3]$ [$Br_2$], $[H^+]$
0.30 0.05, 0.05 5.7×10$^{-5}$
0.30 0.10, 0.05 5.7×10$^{-5}$
0.30 0.10, 0.10 1.2 × 10$^{-4}$
0.40 0.05, 0.20 3.1 × 10$^{-4}$

Based on given data, the rate equations is:

Rate = k$[CH_3COCH_3][H^+ ]$
Rate = k$[CH_3COCH_3][Br_2]$
Rate = k[$[CH_3COCH_3][Br_2][H^+ ]^2$
Rate = k$[CH_3COCH_3][Br_2][H^+ ]$

124.Match the columns

Column-I(Ion) Column-II
(A) $Ti^{2+}$ (p) 2.84
(B) $Zn^{2+}$ (q) 5.92
(C) $Mn^{2+}$ (r) 0
(D) $Sc^{3+}$ (s) 4.90

A – (s), B – (p), C – (q), D – (r).
A – (r), B – (p), C – (q), D – (s).
A – (p), B – (r), C – (q), D – (s).
A – (p), B – (s), C – (q), D – (r).

125. $[Cr(H_2O)_6]Cl_3$ (at n o. of Cr = 24) h as a magn etic moment of 3.83 B. M. The correct distribution of 3d electrons in the Chromium of the complex is

$3d_{xy}^1$, $(3d_{x^2-y^2})^1$, $3d_{yz}^1$
$3d_{xy}^1$, $3d_{yz}^1$, $3d_{xz}^1$
$3d_{xy}^1$, $(3d_{yz})^1$, $3d_{dz}^2$
$(3d_{x^2-y^2})^1$, $3d_z^2$, $3d_{xz}^1$

126.Which one of the following cannot function as an oxidising agent ?

$I^-$
$S_{(s)}$
$NO_{3(aq)}^-$
$Cr_2O_7^{2-}$

127.Identify the reaction which does not liberate hydrogen :

Reaction of lithium hydride with $B_2H_6$
Electrolysis of acidified water using Pt electrodes
Reaction of zinc with aqueous alkali
Allowing a solution of sodium in liquid ammonia to stand

128.Which of the following compounds has the highest boiling point?

$CH_3CH_2CH_2Cl$
$CH_3CH_2CH_2CH_2Cl$
$CH_3CH(CH_3)CH_2Cl$
$(CH_3)_3CCl$

129.When concentrated HCl is added to an aqueous solution of CoCl$_2$ , its colour changes from reddish pink to deep blue. Which complex ion gives blue colour in this reaction?

$[CoCl_4]^{2-}$
$[CoCl_6]^{3-}$
$[CoCl_6]^{4-}$
$[Co(H_2O)_6]^{2+}$

130.Hydrogen has an ionisation energy of 1311 kJ mol$^{-1}$ and for chlorine it is 1256 kJ mol$^{-1}$ . Hydrogen forms H$^+$(aq) ions but chlorine does not form Cl$^+$(aq) ions because

H$^+$ has lower hydration enthalpy
Cl$^+$ has lower hydration enthalpy
Cl has high electron affinity
Cl has high electronegativity

131.The number of enantiomers of the compound $CH_3CHBr CHBr COOH$ is:

2
3
4
6

132.Equivalent weighs of $KMnO_4$ acidic medium,neutral medium and concentrated alkaline medium respectively are M/5, M/1, M/3. Reduced products can be

$MnO_2, MnO_4^{2-},Mn^{2+}$
$MnO_2,Mn^{2+}, MnO_4^{2-}$
$Mn^{2+}, MnO_4^{2-},MnO_2$
$Mn^{2+},MnO_2, MnO_4^{2-}$

133.Which of these have no unit?

Electronegativity
Electron affinity
Ionisation energy
Excitation potential

134.Which of the following statements is not correct for sigma and pi-bonds formed between two carbon atoms?

Sigma-bond determines the direction between carbon atoms but a pi-bond has no primary effect in this regard
Sigma-bond is stronger than a pi-bond
Bond energies of sigma- and pi-bonds are of the order of 264 kJ/mol and 347 kJ/mol, respectively
Free rotation of atoms about a sigma-bond is allowed but not in case of a pi-bond

135.The reactivity of metals with water is in the order of

Na > Mg > Zn >Fe > Cu
Cu > Fe > Zn > Mg > Na
Mg > Zn > Na > Fe > Cu
Zn > Na > Mg > Fe > Cu

CHEMISTRY

Section-B

136.The emf of Daniell cell at 298 K is E$_1$
$Zn|ZnSO_4(0.01M)||CuSO_4(1.0M)|Cu$
When the concentration of $ZnSO_4$ is 1.0M and that of $CuSO_4$ is 0.01M, the emf changed to $E_2$. What is the relation between $E_1$ and $E_2$?

$E_1$ = $E_2$
$E_1$ = 0 ≠ $E_2$
$E_1$ > $E_2$
$E_1$ < $E_2$

137.Through which of the following reactions number of carbon atoms can be increased in the chain?
(i) Grignard reaction
(ii) Cannizzaro’s reaction
(iii) Aldol condensation
(iv) HVZ reaction
Choose the correct option.

Only (iii) and (i)
Only (iii) and (ii)
Only (iii) and (iv)
(i), (ii), (iii) and (iv)

138.The correct order of atomic/ionic sizes is

N < Li < B
$F^-<O^{2-}<N^{3-}$
$Ca^{2+}<S^{2-}<Cl^-$
$Na^+<Mg^{2+}<Cl^-$

139.The rapid change of pH near the stoichiometric point of an acid-base titration is the basis of indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate acid (HIn) and base (In$^-$) forms of the indicator by the expression

$log\frac{In^-}{HIn}$ = $pK_{In}$ - pH
$log\frac{HIn}{In^-}$ = $pK_{In}$ - pH
$log\frac{HIn}{In^-}$ = pH - $pK_{In}$
$log\frac{In^-}{HIn}$ = pH - $pK_{In}$

140.In the diazotization of arylamines with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to

Supress the concentration of free aniline available for coupling
Supress hydrolysis of phenol
Ensure a stoichiometric amount of nitrous acid
Neutralise the base liberated

141.In lake test of Al$^{3+}$ ion, there is formation of coloured floating lake. It is due to

adsorption of litmus by $H_2O$
adsorption of litmus by $Al(OH)_3$
adsorption of litmus by $Al(OH)_4^-$
none of these

142.An ideal gas expands in volume from 1×10$^{-3}$ to 1 × 10$^{-2} m^3$ at 300 K against a constant pressure of 1×10$^5 Nm^{-2}$. The work done is

270 kJ
-900 kJ
-900 kJ
900 kJ

143.Which of the following fact(s) explain as to why p-nitrophenol is more acidic than phenol?
(i) –I Effect of nitro group.
(ii) Greater resonance effect of p-nitrophenoxy group
(iii) Steric effect of bulky nitro group

i and ii
i and iii
ii and iii
ii alone

144.Which of the following reactions will not result in the formation of anisole?

Phenol + dimethyl sulphate in presence of a base
Sodium phenoxide is treated with methyl iodide
Reaction of diazomethane with phenol
Reaction of methylmagnesium iodide with phenol

145.What will be the heat of formation of methane, ifthe heat of combustion of carbon is '–x' kJ, heat of formation of water is '–y' kJ and heat of combustion of methane is 'z' kJ ?

(–x – y + z) kJ
(–z – x + 2y) kJ
(–x – 2y – z) kJ
(–x – 2y + z) kJ

146.The total number of atomic orbitals in fourth energy level of an atom is:

8
16
32
4

147.The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of $Na^+$ will be

-2.55 eV
-5.1 eV
-10.2 eV
+2.55 eV

148.The number of types of bonds between two carbon atoms in calcium carbide is

One sigma, One pi
Two sigma, one pi
Two sigma, two pi
One sigma, two pi

149.Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:

Zero
Infinite
3 Joules
9 Joules

150.pH of a 0.0001 M HCl solution is

4.0
2.0
6.0
7.0

PHYSICS

Section-A

151.Two identical particles move towards each other with velocity 2v and v respectively. The velocity of centre of mass is

v
v/3
v/2
zero.

152.A monoatomic gas at 27°C is compressed adiabatically to 8/27 of its original volume. The rise in temperature will be

300°C
350°C
375°C
400°C

153.A galvanometer can be changed into an ammeter by using

low resistance shunt in series
low resistance shunt in parallel
high resistance shunt in series
high resistance shunt in parallel

154.ABC is a triangular plate of uniform thickness. The sides are in the ratio shown in the figure. $I_{AB}$, $I_{BC}$ and $I_{CA}$ are the moments of inertia of the plate about AB, BC and CA axes respectively. Which one of the following relations is correct?


$I_{AB}$ > $I_{BC}$
$I_{BC}$ > $I_{AB}$
$I_{AB}$ + $I_{BC}$ = $I_{CA}$
$I_{CA}$ is maximum

155.The amplitude of magnetic field of an electromagnetic wave is 2 × 10$^{-7}$T. It's electric field amplitude if the wave is travelling in free space is

$6Vm^{-1}$
$60Vm^{-1}$
$10/6Vm^{-1}$
None of these

156.If c, the velocity of light, g the acceleration due to gravity and P the atmospheric pressure be the fundamental quantities in MKS system, then the dimensions of length will be same as that of

c/g
c/P
Pcg
$c^2/g$

157.A body having initial velocity of 10 m/s moving on a rough surface comes to rest after moving 50 m. What is coefficient of friction between the body and surface? (g = 10 m/s$^2$)

0.5
0.2
0.3
0.1

158.A sonometer wire supports a 4 kg load and vibrates in fundamental mode with a tuning fork of frequency 416 Hz. The length of the wire between the bridges is now doubled. In order to maintain fundamental mode, the load should be changed to

1 kg
2 kg
4 kg
16 kg

159.Given, $_aμ_g$ = $\frac{3}{2}$, $_aμ_w$ = $\frac{4}{3}$, if a convex lens of focal length 10 cm is placed in water, then its focal length in water is

equal to 40 cm
equal to 20 cm
equal to 10 cm
None of these

160.A large tank filled with water to a height ‘h’ is to be emptied through a small hole at the bottom.The ratio of time taken for the level of water to fall from h to h/2 and h/2 to zero is

$√2$
1/$√2$
$√2$-1
1/($√2$-1)

161.A mass is tied to a string and rotated in a vertical circle, the minimum velocity of the body at the top is

$√(gr)$
g/r
$(g/r)^{3/2}$
gr

162.What is the disintegration constant of radon, if the number of its atoms diminishes by 18% in 24 h?

2.1 × 10$^{-3}s^{-1}$
2.1 × 10$^{-4}s^{-1}$
2.1 × 10$^{-5}s^{-1}$
2.1 × 10$^{-6}s^{-1}$

163.Hot water cools from 60°C to 50°C in the first 10 minutes and to 42°C in the next 10 minutes. The temperature of the surroundings is:

25°C
10°C
15°C
20°C

164.Consider the following statement:
When jumping from some height, you should bend your knees as you come to rest, instead of keeping your legs stiff. Which of the following relations can be useful in explaining the statement? Where symbols have their usual meanings.

$∆p_1$ = $∆p_2$
$∆E$ = $∆(PE+KE)$ = 0
$F∆t$ = m$∆v$
$∆x∝∆F$

165.Two capacitors when connected in series have a capacitance of 3μF, and when connected in parallel have a capacitance of 16μF. Their individual capacities are

1μF, 2μF
6μF, 2μF
12μF, 4μF
3μF, 16μF

166.The mass number of He is 4 and that for sulphur is 32. The radius of sulphur nuclei is larger than that of helium by

$√8$
4
2
8

167.The drift current in a p-n junction is

from the n-side to the p-side
from the p-side to the n-side
from the n-side to the p-side if the junction is forward-baised and in the opposite direction if it is reverse biased
from the p-side to the n-side if the junction is forward-baised and in the opposite direction if it is reverse-baised

168.A thin, metallic spherical shell contains a charge Q on it. A point charge q is placed at the cente of the shell and another charge q$_1$ is placed outsideit as shown in figure. All the three charges are positive. The force on the charge at the centre is


towards left
towards right
upward
zero

169.The fermi energy for a substance is

independent of T
directly proportional to $√T$
directly proportional to T
directly proportional to $T^2$

170.If the critical angle for total internal reflection from a medium to vacuum is 30°. Then velocity of light in the medium is

$1.5×10^8m/s$
$2×10^8m/s$
$3×10^8m/s$
$0.75×10^8m/s$

171.A metal piece is heated upto T$^0$ abs. The temperature of the surrounding is t$^0$ abs.The heat in the surrounding due to radiation is proportional to

$(T-T)^4$
$T^4-t^4$
$(T-t)^{1/4}$
$T^2-t^2$

172.The rain drops are in spherical shape due to

residual pressure
thrust on drop
surface tension
viscosity

173.An iron rod of length 2m and cross-sectional area of 50 mm$^2$ is stretched by 0.5 mm, when a mass of 250 kg is hung from its lower end. Young’s modulus of iron rod is

$19.6×10^{20} N/m^2$
$19.6×10^{18} N/m^2$
$19.6×10^{10} N/m^2$
$19.6×10^{15} N/m^2$

174.A particle of mass 1 kg is moving in S.H.M. with an amplitude 0.02 and a frequency of 60 Hz. The maximum force acting on the particle is

$144π^2$
$188π^2$
$288π^2$
None of these

175.A dip circle is so set that its needle moves freely in the magnetic meridian. In this position, the angle of dip is 40$^0$. Now the dip circle is rotated so that the plane in which the needle moves makes an angle of 30$^0$ with the magnetic meridian. In this position, the needle will dip by an angle

40$^0$
30$^0$
more than 40$^0$
less than 40$^0$

176.According to Maxwell’s hypothesis, a changing electirc field gives rise to

an e.m.f
magnetic field
electric current
pressure gradient.

177.The unit vector along 2î – 3ĵ + k̂ is

$\frac{2î – 3ĵ + k̂}{√14}$
$\frac{2î – 3ĵ + k̂}{5}$
$\frac{2î – 3ĵ + k̂}{√15}$
None of these

178.A bucket full of hot water is kept in a room and it cools from 75$^0$C to 70$^0$C in T$_1$ minutes, from 70$^0$C to 65$^0$C in $T_2$ minutes and from 65$^0$C to 60$^0$C in $T_3$ minutes. Then

$T_1=T_2=T_3$
$T_1<T_2<T_3$
$T_1>T_2>T_3$
$T_1<T_2>T_3$

179.A man measures the period of a simple pendulum inside a stationary lift and finds it to be T s. If the lift accelerates upwards with an acceleration g / 4, then the period of the pendulum will be


T
T/4
$\frac{2T}{√5}$
2T√5

180.The energy of hydrogen atom in the $n^{th}$ orbit is $E_n$, then the energy in the $n^{th}$ orbit of single ionised helium atom is

$E_n$/2
2$E_n$
4$E_n$
$E_n$/4

181.A Carnot engine absorbs 1000 J of heat energy from a reservoir at 127°C and rejects 600 J of heat energy during each cycle. The efficiency of engine and temperature of sink will be:

20% and – 43°C
40% and – 33°C
50% and – 20°C
70% and – 10°C

182.A cubical block of side 30 cm is moving with velocity 2 ms$^{-1}$ on a smooth horizontal surface. The surface has a bump at a point O as shown in figure. The angular velocity (in rad/s) of the block immediately after it hits the bump, is


13.3
5.0
9.4
6.7

183.A body moves in a circular orbit of radius R under the action of a central force. Potential due to the central force is given by V(r) = kr (k is a positive constant). Period of revolution of the body is proportional to :

$R^{1/2}$
$R^{-1/2}$
$R^{-3/2}$
$R^{-5/2}$

184.Three identical spheres each of radius R are placed touching each other on a horizontal table as shown in figure. The co-ordinates of centre of mass are ;


(R, R)
(0, 0)
(R/2, R/2)
(R, R/√3)

185.A charge q is moving with a velocity v parallel to a magnetic field B. Force on the charge due to magnetic field is

q v B
q B/v
zero
B v/q

PHYSICS

Section-B

186.The current in a coil of L = 40 mH is to be increased uniformly from 1A to 11A in 4 milli sec. The induced e.m.f. will be

100 V
0.4 V
440 V
40 V

187.The separation between successive fringes in a double slit arrangement is x. If the whole arrangement is dipped under water what will be the new fringe separation? [The wavelenght of light being used is 5000 Å]

1.5 x
x
0.75 x
2 x

188.Time required to boil 2 litres of water initially at 20°C by a heater coil which works at 80% efficiency spending 500 joule/s is

82 minutes
50 minutes
28 minutes
37 minutes

189.The frequencies of X-rays, g-rays and ultraviolet rays are respectively a, b, and c. Then

a < b, b < c
a < b, b > c
a > b, b > c
a > b, b < c

190.A ray of light is incident on the surface of separation of a medium with the velocity of lightat an angle 45° and is refracted in the medium atan angle 30°. Velocity of light in the medium will be (velocity of light in air = $3 × 10^8 m/s$

$3.8 × 10^8 m/s$
$3.38 × 10^8 m/s$
$2.12 × 10^8 m/s$
$1.56 × 10^8 m/s$

191.An element of 0.05î m is placed at the origin as shown in the figure which carries a large current of 10 A. distance of 1 m in perpendicular direction. The value of magnetic field is


4.5 × 10$^{-8}$ T
5.5 × 10$^{-8}$ T
5.0 × 10$^{-8}$ T
7.5 × 10$^{-8}$ T

192.Which of the following statements is FALSE for a particle moving in a circle with a constant angular speed ?

The acceleration vector points to the centre of the circle
The acceleration vector is tangent to the circle
The velocity vector is tangent to the circle
The velocity and acceleration vectors are perpendicular to each other.

193.If an alternating current is flowing in a spring, then the spring will be changing

in a straight line
periodically
elliptically
first elliptically then in a straight line

194.A ball of mass 1 kg bounces against the ground as shown in the figure. The approaching velocity is 25 m/s and the velocity after hitting the ground is 20 m/s. The impulse exerted on the ball is :


7.8 N - s
27.68 N - s
31 N - s
62 N - s

195.A man projects a coin upwards from the gate of a uniformly moving train. The path of coin for the man will be

parabolic
inclined straight line
vertical straight line
horizontal straight line

196.Potential at any point inside a charged hollow sphere

increases with distance
is a constant
decreases with distance from center
is zero

197.Two resistances R and 2R are connected in parallel in an electric circuit. The thermal energy developed in R and 2R are in the ratio of

1:2
2:1
1:4
4:1

198.A coil carrying electric current is placed in uniform magnetic field

torque is formed
e.m.f. is induced
Both of these
None of these

199.In an LCR circuit capacitance is changed from C to 2C. For the resonant frequency to remain unchanged, the inductance should be changed from L to

L/2
2L
4L
L/4

200.The distance travelled by light in glass (refractive index 1.5) in a nano second will be

20 cm
30 cm
45 cm
40 cm